New carbon-nanotube films improve prospects of solar energy devices
February 26, 2013
New research by Yale University scientists helps pave the way for the next generation of solar cells, a renewable energy technology that directly converts solar energy into electricity.
These films could be used to produce hybrid carbon/silicon solar cells with far greater power-conversion efficiency than reported to date.
“Our approach bridges the cost-effectiveness and excellent electrical and optical properties of novel nanomaterials with well-established, high efficiency silicon solar cell technologies,” said André D. Taylor, assistant professor of chemical and environmental engineering at Yale and a principal investigator of the research.
Silicon, an abundant element, is an ideal material for solar cells because its optical properties make it an intrinsically efficient energy converter. But the high cost of processing single-crystalline silicon at necessarily high temperatures has hindered widespread commercialization.
Organic solar cells — an existing alternative to high-cost crystalline silicon solar cells — allow for simpler, room-temperature processing and lower costs, researchers said, but they have low power-conversion efficiency.
Hybrid silicon-carbon solar cell architecture
So instead of using only organic substitutes, the Yale team applied thin, smooth carbon nanotube films with superior conductance and optical properties to the surface of single crystalline silicon to create a hybrid solar cell architecture. To do it, they developed a method called superacid sliding.
The approach allows them to take advantage of the desirable photovoltaic properties of single-crystalline silicon through a simpler, low-temperature, lower-cost process. It allows for both high light absorption and high electrical conductivity, with a record power conversion efficiency of more than 11 percent for CNT/Si solar cells and simple, low-cost processes. (Conversion efficiency is the ratio of the electrical output of a solar cell to the incident energy in the form of sunlight.)
“This is striking, as it suggests that the superior photovoltaic properties of single-crystalline silicon can be realized by a simple, low-temperature process,” said Xiaokai Li, a doctoral student in Taylor’s lab and a lead author on both papers. “The secret lies in the arrangement and assembly of these carbon nanotube thin films,”
“Optimizing this interface could also serve as a platform for many next-generation solar cell devices, including carbon nanotube/polymer, carbon/polymer, and all carbon solar cells,” said Yeonwoong (Eric) Jung, a postdoctoral researcher in Reed’s lab and also a lead author of the papers.
The National Science Foundation, NASA, the U.S. Department of Energy, and the Yale Institute for Nanoscience and Quantum Engineering provided support for the research.
- Yeonwoong Jung et al., Record High Efficiency Single-Walled Carbon Nanotube/Silicon p–n Junction Solar Cells, Nano Letters, 2013, DOI: 10.1021/nl3035652
- Xiaokai Li et al., Improved efficiency of smooth and aligned single walled carbon nanotube/silicon hybrid solar cells, Energy & Environmental Science, 2012, DOI: 10.1039/C2EE23716D