Tapping more of the sun’s energy using heat as well as light

New approach developed at MIT could generate power from sunlight efficiently and on demand
January 24, 2014

A nanophotonic solar thermophotovoltaic device composed of an array of multi‑walled carbon nanotubes as the absorber, a one‑dimensional silicon/silicon dioxide photonic crystal as the emitter, and a 0.55 eV photovoltaic cell (credit: John Freidah)

A new approach to harvesting solar energy, developed by MIT researchers, could improve efficiency by using sunlight to heat a high-temperature material whose infrared radiation would then be collected by a conventional photovoltaic cell.

This technique could also make it easier to store the energy for later use, the researchers say.

In this case, adding the extra step improves performance, because it makes it possible to take advantage of wavelengths of light that ordinarily go to waste. The process is described in a paper published this week in the journal Nature Nanotechnology.

A conventional silicon-based solar cell “doesn’t take advantage of all the photons,”  associate professor of mechanical engineering Evelyn Wang explains. That’s because converting the energy of a photon into electricity requires that the photon’s energy level match that of a characteristic of the photovoltaic (PV) material called a bandgap. Silicon’s bandgap responds to many wavelengths of light, but misses many others.

Collecting a broad spectrum of light

To address that limitation, the team inserted a two-layer absorber-emitter device — made of novel materials including carbon nanotubes and photonic crystals — between the sunlight and the PV cell. This intermediate material collects energy from a broad spectrum of sunlight, heating up in the process. When it heats up, as with a piece of iron that glows red hot, it emits light of a particular wavelength, which in this case is tuned to match the bandgap of the PV cell mounted nearby.

This basic concept has been explored for several years, since in theory such solar thermophotovoltaic (STPV) systems could provide a way to circumvent a theoretical limit on the energy-conversion efficiency of semiconductor-based photovoltaic devices. That limit, called the Shockley-Queisser limit, imposes a cap of 33.7 percent on such efficiency, but Wang says that with TPV systems, “the efficiency would be significantly higher — it could ideally be over 80 percent.”

There have been many practical obstacles to realizing that potential; previous experiments have been unable to produce a STPV device with efficiency of greater than 1 percent. But the researchers have already produced an initial test device with a measured efficiency of 3.2 percent, and they say with further work they expect to be able to reach 20 percent efficiency — enough, they say, for a commercially viable product.

The design of the two-layer absorber-emitter material is key to this improvement. Its outer layer, facing the sunlight, is an array of multiwalled carbon nanotubes, which very efficiently absorbs the light’s energy and turns it to heat. This layer is bonded tightly to a layer of a photonic crystal, which is precisely engineered so that when it is heated by the attached layer of nanotubes, it “glows” with light whose peak intensity is mostly above the bandgap of the adjacent PV, ensuring that most of the energy collected by the absorber is then turned into electricity.

In their experiments, the researchers used simulated sunlight, and found that its peak efficiency came when its intensity was equivalent to a focusing system that concentrates sunlight by a factor of 750. This light heated the absorber-emitter to a temperature of 962 degrees Celsius.

This level of concentration is already much lower than in previous attempts at STPV systems, which concentrated sunlight by a factor of several thousand. But the MIT researchers say that after further optimization, it should be possible to get the same kind of enhancement at even lower sunlight concentrations, making the systems easier to operate.

Such a system, the team says, combines the advantages of solar photovoltaic systems, which turn sunlight directly into electricity, and solar thermal systems, which can have an advantage for delayed use because heat can be more easily stored than electricity. The new solar thermophotovoltaic systems, they say, could provide efficiency because of their broadband absorption of sunlight; scalability and compactness, because they are based on existing chip-manufacturing technology; and ease of energy storage, because of their reliance on heat.

Some of the ways to further improve the system are quite straightforward. Since the intermediate stage of the system, the absorber-emitter, relies on high temperatures, its size is crucial: The larger an object, the less surface area it has in relation to its volume, so heat losses decline rapidly with increasing size. The initial tests were done on a 1-centimeter chip, but follow-up tests will be done with a 10-centimeter chip, they say.

The work was funded by the U.S. Department of Energy through MIT’s Solid-State Solar Thermal Energy Conversion (S3TEC) Center, as well as the Martin Family Society, the MIT Energy Initiative, and the National Science Foundation.

Abstract of Nature Nanotechnology paper

The most common approaches to generating power from sunlight are either photovoltaic, in which sunlight directly excites electron–hole pairs in a semiconductor, or solar–thermal, in which sunlight drives a mechanical heat engine. Photovoltaic power generation is intermittent and typically only exploits a portion of the solar spectrum efficiently, whereas the intrinsic irreversibilities of small heat engines make the solar–thermal approach best suited for utility-scale power plants. There is, therefore, an increasing need for hybrid technologies for solar power generation. By converting sunlight into thermal emission tuned to energies directly above the photovoltaic bandgap using a hot absorber–emitter, solar thermophotovoltaics promise to leverage the benefits of both approaches: high efficiency, by harnessing the entire solar spectrum; scalability and compactness, because of their solid-state nature; and dispatchablility, owing to the ability to store energy using thermal or chemical means. However, efficient collection of sunlight in the absorber and spectral control in the emitter are particularly challenging at high operating temperatures. This drawback has limited previous experimental demonstrations of this approach to conversion efficiencies around or below 1%. Here, we report on a full solar thermophotovoltaic device, which, thanks to the nanophotonic properties of the absorber–emitter surface, reaches experimental efficiencies of 3.2%. The device integrates a multiwalled carbon nanotube absorber and a one-dimensional Si/SiO2 photonic-crystal emitter on the same substrate, with the absorber–emitter areas optimized to tune the energy balance of the device. Our device is planar and compact and could become a viable option for high-performance solar thermophotovoltaic energy conversion.