3D microvascular network allows for repeated self-healing in composite materials
April 18, 2014
Researchers at the Beckman Institute for Advanced Science and Technology at the University of Illinois at Urbana-Champaign have created a 3D vascular system that allows high-performance composite materials such as fiberglass to heal autonomously and repeatedly.
Internal damage in fiber-reinforced composites, which are used in structures of modern airplanes and automobiles, is difficult to detect and nearly impossible to repair by conventional methods. A small, internal crack can quickly develop into irreversible damage from delamination, a process in which the layers separate. This remains one of the most significant factors limiting more widespread use of composite materials.
Hidden healing vascular networks
However, fiber-composite materials can now heal autonomously through the new self-healing system.Professors Nancy Sottos, Scott White, and Jeff Moore and their team created 3D vascular networks — patterns of microchannels filled with healing chemistries — that thread through a fiber-reinforced composite. When damage occurs, the networks within the material break apart and allow the healing chemistries to mix and polymerize, autonomously healing the material over multiple cycles.
These results were detailed in a paper titled “Continuous self-healing life cycle in vascularized structural composites,” published in Advanced Materials.
“This is the first demonstration of repeated healing in a fiber-reinforced composite system,” said Scott White, aerospace engineering professor and co-corresponding author. “Self-healing has been done before in polymers with different techniques and networks, but they couldn’t be translated to fiber-reinforced composites. The missing link was the development of the vascularization technique.”
“The beauty of this self-healing approach is, we don’t have to probe the structure and say, this is where the damage occurred and then repair it ourselves,” said Jason Patrick, a Ph.D. candidate in civil engineering and lead author.
The vasculature within the system integrates dual networks that are isolated from one other. Two liquid healing agents (an epoxy resin and hardener) are sequestered in two different microchannel networks.
“When a fracture occurs, this ruptures the separate networks of healing agents, automatically releasing them into the crack plane — akin to a bleeding cut,” Patrick said. “As they come into contact with one another in situ, or within the material, they polymerize [combine into more complex molecules] to essentially form a structural glue in the damage zone. We tested this over multiple cycles and all cracks healed successfully at nearly 100 percent efficiency.”
To allow the healing agents to combine effectively after being released within the crack, the vessels were overlapped to further promote mixing of the liquids, which both have a consistency similar to maple syrup.
Fiberglass and other composite materials are widely used in aerospace, automotive, naval, civil, and even sporting goods because of their high strength-to-weight ratio — they pack a lot of structural strength into a very lean package. However, because the woven laminates are stacked in layers, it is easier for the structure to separate between the layers, making this self-healing system a promising solution to a long-standing problem and greatly extending their lifetime and reliability.
A vasculature for self-healing
“Additionally, creating the vasculature integrates seamlessly with typical manufacturing processes of polymer composites, making it a strong candidate for commercial use,” said Nancy Sottos, materials science and engineering professor and co-corresponding author.
Fiber-composite laminates are constructed by weaving and stacking multiple layers of reinforcing fabric, which are then co-infused with a binding polymer resin. Using that same process, the researchers stitched in a sort of fishing line, made from a bio-friendly polymer and coined “sacrificial fiber,” within the composite. Once the composite was fabricated, the entire system was heated to melt and evaporate the sacrificial fibers, leaving behind hollow microchannels, which became the vasculature for the self-healing system.
This work was supported by the Air Force Office of Scientific Research, the Department of Homeland Security Center of Excellence for Explosives Detection, Mitigation, and Response, and the Army Research Laboratory.
Abstract of Advanced Materials paper
By incorporating 3D microvascular networks containing a two-part reactive chemistry within a fiber-reinforced composite, continuous cycles of self-healing after interlaminar delamination are achieved. An interpenetrating vasculature shows improved in situ fluid mixing over segregated microchannels, resulting in full recovery (>100%) of mode-I fracture resistance.