Graphite enters different states of matter in ultrafast experiment
May 17, 2012
For the first time, scientists have seen an X-ray-irradiated mineral go to two different states of matter in about 40 femtoseconds (a femtosecond is one quadrillionth of a second).
Using the Linac Coherent Light Source (LCLS) X-ray Free-Electron Laser (XFEL) at SLAC National Accelerator Laboratory at Stanford, Stefan Hau-Riege of Lawrence Livermore National Laboratory and colleagues heated graphite to induce a transition from solid to liquid and to warm-dense plasma.
Ultrafast phase transitions from solid to liquid and plasma states are important in the development of new material-synthesis techniques, in ultrafast imaging, and high-energy density science.
By using different pulse lengths and calculating different spectra, the team was able to extract the time dependence of plasma parameters, such as electron and ion temperatures and ionization states.
“We found that the heating and disintegration of the ion lattice occurs much faster than anticipated,” Hau-Riege said.
The research provides new insights into the behavior of matter irradiated by intense hard X-rays. Though the study ultimately serves as a breakthrough in plasma physics and ultrafast materials science, it also affects other fields such as single molecule biological imaging and X-ray optics.
For single-molecule bioimaging, the team found that in certain cases it may be substantially more difficult than anticipated because energy transfer is surprisingly fast. In X-ray optics, they found that the damage threshold is lower than anticipated.
This is the first XFEL high-energy density science experiment that used inelastic X-ray scattering as a plasma diagnostic.
In addition to SLAC National Accelerator Laboratory, participating institutions include Universitat Duisburg-Essen; Max Planck Advanced Study Group, Center for Free Electron Laser Science; Max Planck Institut fur medizinische Forschung; and Max Planck Institut fur Kernphysik, all of Germany.
Ref.: Forthcoming in May 21 edition of Physical Review Letters.